Single and double reduction of C60 in 2:1 γ-cyclodextrin/[60]fullerene inclusion complexes by cyclodextrin radicals
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Single and double reduction of C60 in 2:1 γ- cyclodextrin/[60]fullerene inclusion complexes by cyclodextrin radicals
Spectroscopic and chemical properties of γ-CD• radicals, resulting from the abstraction by HO• radicals of hydrogen atoms, have been investigated using pulse radiolysis. The reactions of γ-CD• radicals with C60 in 2:1 γ-CD/C60 inclusion complexes have been studied in aqueous solutions. It has been demonstrated that the γ-CD_ radicals are reducing species producing C60 monoanion radicals, as wel...
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ژورنال
عنوان ژورنال: Chemical Physics
سال: 2008
ISSN: 0301-0104
DOI: 10.1016/j.chemphys.2008.10.014